Overview

BRIDGE DECK
Science office
Technical support office
Operations office
Nitrogen generator

CORE DECK
Core receiving
Core splitting/sampling
Core description
Microscopy
Paleomagnetism
Paleontology prep
Petrophysics
Stratigraphic correlation
Downhole measurements
Electronics shop
Science container
Lab chemicals

FO'C'S'LE DECK
Chemistry
Microbiology
Thin section
X-ray
Sample preparation
Conference room
Imaging office
Publications office
Staff office
Hospital
Lab chemicals

MAIN DECK
Mess hall, galley, laundry

'TWEEN DECK (forward)
Recreation

'TWEEN DECK (lower)
Computer & data services

HOLD DECK
Core storage

FANTAIL
Underway geophysics

Accommodations

Ship's systems

Fo'c's'le Deck: Chemistry Lab

Function

The Chemistry laboratory is used by shipboard scientists to conduct organic and inorganic geochemical analyses. A primary responsibility of the organic geochemists is to provide hydrocarbon data for safety and environmental concerns. In addition, instruments are available for determining the source, amount, and maturity of organic matter; carbonate content; and total carbon, nitrogen, and sulfur.

Inorganic geochemists have a wide array of analytical instruments at their disposal for determination of a large range of interstitial water constituents that typically include pH, alkalinity, chloride, calcium, magnesium, sulfate, potassium, strontium, sodium, manganese, phosphate, silica, and ammonium. Two Laboratory specialists provide dedicated, 24-hour technical support. More...

Instruments

• Agilent 6890 Gas Chromatograph with flame ionization detector (FID) detector
• Agilent 6890 Gas Chromatograph with flame ionization (FID) and thermal conductivity detectors (TCD)
• Agilent 6890 Gas Chromatograph with Agilent 5973 mass selective detector (MSD)
• Brinkmann 702 SM Titrino autotitrators
• Cahn Model 31 Microbalance (samples <100 mg)
• Carver hydraulic presses
• Coulometrics CM5011 Coulometer
• Dionex Corporation ICS3000 Ion Chromatograph
• Horiba-Jobin-Yvon JY 2000 Ultrace ICP-AES
• Humble Instruments Source Rock (SR) Analyzer
• Mettler-Toledo XS204 dual-balance system (samples >100 mg to 200 g)
• OI Corporation DA3500 Discrete Analyzer
• Thermo Electron Flash EA 1112 Element Analyzer (CHNS)

Organic Geochemistry

Safety Monitoring

Organic geochemists perform a vital function on the ship by providing routine safety monitoring for hydrocarbon gases. Typically, a ~5 cm³ sediment headspace sample is collected at a frequency of one/core, heated, and the evolved gases are analyzed with a gas chromatograph (GC). When gas pockets are detected in the core liner, a vacutainer sample can be taken to sample the gas directly. One Agilent 6890 GC is equipped with an FID detector for rapid determination of methane, ethane, ethylene, propane, and propylene. The second Agilent 6890 GC is equipped with FID and TCD detectors to measure hydrocarbons from methane to hexane. In addition, nonhydrocarbon gases such as hydrogen sulfide, oxygen, nitrogen, carbon dioxide, and carbon monoxide can be analyzed at the same time as hydrocarbon gases.

High–Molecular-Weight Hydrocarbons and Organic Matter

A third Agilent 6890 GC with an Agilent 5973 MSD is available for analysis of semi-volatile organic-soluble constituents. A Humble Instruments Source Rock (SR) Analyzer uses a pyrolysis technique to identify the type and maturity of organic matter.

Elemental Analysis

Sediment samples can also be analyzed for total carbon, nitrogen, sulfur, and carbonate carbon. The total organic carbon of the sediment can be determined by calculating the difference between total carbon and carbonate carbon. Carbonate carbon is measured by coulometric titration using a Coulometrics CM5011 analyzer. A Thermo Electron Flash EA 1112 Element Analyzer is used to determine total carbon, nitrogen, and sulfur.

Inorganic Geochemistry

Shipboard interstitial (pore) water analyses are typically performed on waters extracted from 5–10 cm³ whole-round sections. The routine shipboard interstitial water sampling program calls for one whole-round sample to be taken per core for the first six cores, and one sample every third core thereafter. Pore water is extracted from core samples by applying pressures up to 40,000 lb (~4150 psi) with a Carver hydraulic press. Immediately after extraction and filtration, aliquots are analyzed for salinity using a hand-held particular refractometer, and for pH and alkalinity using Brinkmann 702 SM autotitrators.

Chloride is also determined by titration. A variety of nutrients and other pore water constituents (e.g., ammonium, silica, phosphate, nitrate, and nitrite) can be determined using an OI Corporation DA3500 Discrete Analyzer (multiwavelength automated color spectrometer). Numerous cations and anions can be analyzed using a Dionex ICS3000 Ion Chromatograph (e.g., calcium, magnesium, sulfate). A variety of other elements can be determined by inductively coupled plasma–atomic emission spectrometry on a Horiba-Jobin-Yvon JY 2000 Ultrace ICP-AES. A typical suite of elements determined for interstitial water samples includes Sr, Li, Fe, Mn, B, and Ba. In addition, hard rock samples can be analyzed for all major and minor elements.

See all chemicals used in shipboard labs.